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龙胆紫

时间:2023-07-15  来源:化工号   作者:C25H30ClN3
  • 结晶紫
  • 龙胆紫
  • 盐基品紫
  • 碱性青莲
  • 碱性紫 3
  • 碱性紫6BN
  • 碱性紫5BN
  • 碱性艳紫3B
  • 中文名 龙胆紫
    英文名 Basic Violet 3
    别名 结晶紫
    龙胆紫
    盐基品紫
    碱性青莲
    碱性紫 3
    碱性紫6BN
    碱性紫5BN
    碱性艳紫3B
    英文别名 Badil
    Vianin
    Axuris
    Viocid
    adergon
    Meroxyl
    S NO 785
    Andergon
    gentersal
    Meroxylan
    VIOLET 7B
    Pyoktanin
    violet cp
    Gentiaverm
    C.I. 42555
    GRAM STAIN
    violet 5bo
    violet 6bn
    paper blue r
    PYOKTANIN BLUE
    bismuth violet
    BASIC VIOLET 3
    Basic Violet 3
    hecto violet r
    Gentian violet
    Aniline violet
    Crystal violet
    basic violet bn
    meroxylanwander
    GRAM STAIN NO 1
    genetian violet
    BRILLIANT VIOLET
    crystal violet o
    crystal violet ao
    crystal violet fn
    crystal violet ss
    Hectograph violet
    crystal violet 6b
    Hexamethyl Violet
    crystal violet hl2
    crystal violet 10b
    crystal violet aon
    crystal violet 6bo
    crystal violet bpc
    crystal violet 5bo
    C.I. Basic violet 3
    crystal violet base
    brilliant violet 58
    C.I. Basic Violet 1
    Brilliant Violet 5B
    CALCOZINE VIOLET 6BN
    calcozine violet 6bn
    aizen crystal violet
    hectograph violet sr
    mitsui crystal violet
    hidaco crystal violet
    plastoresin violet 5bo
    C.I. Basic Violet 3 (8CI)
    Methylrosaniline Chloride
    aniline violet pyoktanine
    Methylrosanilinium chloride
    hexamethyl-p-rosaniline chloride
    hexamethylparaosaniline chloride
    hexamethyl-p-rosaniline hydrochloride
    pararosaniline, N,N,N',N',N'',N''-hexamethyl-, chloride
    ((4-bis(p-(dimethylamino)phenyl)methylene)-2,5-cyclohexadien-1-ylidene)dimethylammonium chloride
    Methanaminium, N-[4-[bis[4-(dimethylamino)phenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride
    CAS 548-62-9
    EINECS 208-953-6
    化学式 C25H30ClN3
    分子量 407.99
    InChI InChI=1/C25H30N3.ClH/c1-26(2)22-13-7-19(8-14-22)25(20-9-15-23(16-10-20)27(3)4)21-11-17-24(18-12-21)28(5)6;/h7-18H,1-6H3;1H/q+1;/p-1
    InChIKey ZXJXZNDDNMQXFV-UHFFFAOYSA-M
    密度 1.19 g/cm3 at 20 °C
    熔点 205 °C (dec.) (lit.)
    沸点 560.86°C (rough estimate)
    闪点 40°C
    水溶性 16 g/L (25 ºC)
    蒸汽压 0Pa at 25℃
    溶解度 water: soluble50g/L at 27°C
    折射率 1.6010 (estimate)
    酸度系数 9.4(at 25℃)
    PH值 2.5-3.5 (10g/l, H2O, 20℃)
    存储条件 room temp
    稳定性 Stable. Incompatible with strong oxidizing agents, strong acids. Light-sensitive. Combustible.
    敏感性 Sensitive to light
    外观 Solid
    颜色 S. No.: 785
    气味 Slight characteristic odor
    最大波长(λmax) ['590nm']
    Merck 14,4395
    BRN 4077708
    物化性质 ​溶于水、乙醇和氯仿,不溶于乙醚。水溶液和乙醇溶液呈深紫色,遇浓硫酸显橙色。
    暗绿色闪光粉末或粒子。溶于冷水和热水,呈紫色,极易溶于乙醇。于浓硫酸中呈红黄色,稀释后呈暗绿光黄色,然后转变成蓝和紫色。染棉纤维日晒牢度为 1-2 级,染腈纶纤维日晒牢度为 2-3 级。
    产品用途 用作生物染色剂
    MDL号 MFCD00011750
    危险品标志 Xn - 有害物品
    有害物品
    N - 危害环境的物品
    危害环境的物品
    T - 有毒物品
    有毒物品
    C - 腐蚀性物品
    腐蚀性物品
    风险术语 R52/53 -
    R50/53 - 对水生生物有极高毒性,可能对水体环境产生长期不良影响。
    R45 - 可能致癌。
    R41 - 对眼睛有严重伤害。
    R22 - 吞食有害。
    R40 - 少数报道有致癌后果。
    R34 - 引起灼伤。
    R10 - 易燃。
    R36/37/38 - 刺激眼睛、呼吸系统和皮肤。
    R23/25 - 吸入及吞食有毒。
    R51/53 - 对水生生物有毒,可能对水体环境产生长期不良影响。
    R68 - 可能有不可逆后果的危险。
    安全术语 S61 - 避免释放至环境中。参考特别说明/安全数据说明书。
    S60 - 该物质及其容器须作为危险性废料处置。
    S53 - 避免接触,使用前须获得特别指示说明。
    S45 - 若发生事故或感不适,立即就医(可能的话,出示其标签)。
    S46 - 若不慎吞食,立即求医并出示其容器或标签。
    S36/37/39 - 穿戴适当的防护服、手套和护目镜或面具。
    S26 - 不慎与眼睛接触后,请立即用大量清水冲洗并征求医生意见。
    S39 - 戴护目镜或面具。
    S36/37 - 穿戴适当的防护服和手套。
    S16 - 远离火源。
    S22 - 切勿吸入粉尘。
    危险品运输编号 UN 3077 9/PG 3
    WGK Germany 3
    RTECS BO9000000
    TSCA Yes
    海关编号 32041300
    Hazard Class 9
    Packing Group III
    上游原料 硫酸 硫酸钠 苯乙酮 N-甲基苯胺 芥酸酰胺 4,4'-二(N,N-二甲氨基)二苯基甲醇 N,N-二甲基苯胺 光气
    下游产品 乙醇胺 三乙醇胺 二乙醇胺 氯乙烷 颜料紫 3 (1RS,2RS)-2-硝基-1-苯基三亚甲基双醛酸酯 4,4'-二(N,N-二甲氨基)二苯基甲醇
    参考资料 展开查看 1. 陈周利 徐洁玲. ICU鲍曼不动杆菌耐药性与生物膜相关性研究[J]. 临床医学工程(3期):121-122.
    2. 武坤 袁峰 祝艳翠 等. miR-152对SHI-1细胞增殖 转移及致瘤性的调控机制[J]. 中国实验血液学杂志 2019 027(005):1455-1462.
    3. 李宏伟, 慈百全, 侯明磊,等. 鸡源乳酸菌的分离鉴定及其生物学特性分析[J]. 江苏农业科学, 2020(13).
    4. 杜金童. CDK1在胰腺癌中的生物学功能、临床意义及相关抑制剂研究[D].山东大学,2020.
    5. 马伏宁,黄东梅,宋顺,吴斌,郭刚,王达新,谭琳.山地五月茶提取物对乳腺癌细胞MDA-MB-231增殖的抑制活性研究[J].热带作物学报,2020,41(08):1693-1699.
    6. 江宇航,李宏伟,杨晓洁,林连兵,张棋麟.马尾松毛虫肠道产细菌素细菌的筛选及抑菌特性[J].微生物学通报,2021,48(01):123-134.
    7. Ya-Ping Jiang, Rui-Juan Ye, Jia-Mei Yang, Ning Liu, Wen-Jin Zhang, Lin Ma, Tao Sun, Jian-Guo Niu, Ping Zheng, Jian-Qiang Yu, Protective effects of Salidroside on spermatogenesis in streptozotocin induced type-1 diabetic male mice by inhibiting oxidative st
    8. Li, Xi‐Mei, et al. "3D Aluminum Hybrid Plasmonic Nanostructures with Large Areas of Dense Hot Spots and Long‐Term Stability." Advanced Functional Materials 27.10 (2017): 1605703.https://doi.org/10.1002/adfm.201605703
    9. [IF=14.919] Tian Li et al."Liquid-state quantitative SERS analyzer on self-ordered metal liquid-like plasmonic arrays."Nat Commun. 2018 Sep;9(1):1-12
    10. [IF=2.649] Jianqing Li et al."Production of Composite Scaffold Containing Silk Fibroin, Chitosan, and Gelatin for 3D Cell Culture and Bone Tissue Regeneration."Med Sci Monitor. 2017; 23: 5311–5320
    11. [IF=13.273] Yiru Gao et al."Microwave-triggered ionic liquid-based hydrogel dressing with excellent hyperthermia and transdermal drug delivery performance."Chem Eng J. 2022 Feb;429:131590
    12. [IF=6.707] Muhammad Shafi et al."Highly efficient SERS substrates with different Ag interparticle nanogaps based on hyperbolic metamaterials."Appl Surf Sci. 2021 Jul;555:149729
    13. [IF=6.244] Ye Yun et al."miR-100-5p Downregulates mTOR to Suppress the Proliferation, Migration, and Invasion of Prostate Cancer Cells."Front Oncol. 2020 Dec;0:2695
    14. [IF=6.15] Si-lin Lv et al."Lp-PLA2 inhibition prevents Ang II-induced cardiac inflammation and fibrosis by blocking macrophage NLRP3 inflammasome activation."Acta Pharmacol Sin. 2021 Jul;:1-17
    15. [IF=3.825] Xiaoxiong Xiao et al."Silencing of UAP1L1 inhibits proliferation and induces apoptosis in esophageal squamous cell carcinoma."Mol Carcinogen. 2021 Mar;60(3):179-187
    16. [IF=3.407] Ya-Ping Jiang et al."Protective effects of Salidroside on spermatogenesis in streptozotocin induced type-1 diabetic male mice by inhibiting oxidative stress mediated blood-testis barrier damage."Chem-Biol Interact. 2020 Jan;315:108869
    17. [IF=3.375] Lifeng Dong et al."MiR-34b-5p inhibits cell proliferation, migration and invasion through targeting ARHGAP1 in breast cancer."Am J Transl Res. 2020; 12(1): 269–280
    18. [IF=2.967] Yuyang Tian et al."Association between miR‑212‑3p and SOX11, and the effects of miR‑212‑3p on cell proliferation and migration in mantle cell lymphoma."Oncol Lett. 2021 Oct;22(4):1-8
    19. [IF=2.754] Dong Wenjie et al."Circ-KIAA0907 inhibits the progression of oral squamous cell carcinoma by regulating the miR-96-5p/UNC13C axis."World J Surg Oncol. 2021 Dec;19(1):1-13
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    21. [IF=2.081] Xiaohui CHEN et al."Electrochemiluminescence Quenching Sensor of Carboxylic Carbon Nanotubes Modified Glassy Carbon Electrode for Detection of Crystal Violet Based on Nitrogen-doped Graphene Quantum Dots @ Peroxydisulfate System."Analytical Sciences. 2019
    22. [IF=2.055] Shufang Hu et al."Astragaloside IV inhibits cell proliferation and metastasis of breast cancer via promoting the long noncoding RNA TRHDE-AS1."J Nat Med-Tokyo. 2021 Jan;75(1):156-166
    23. [IF=5.076] Jihua Xu et al.Facilely Flexible Imprinted Hemispherical Cavity Array for Effective Plasmonic Coupling as SERS Substrate.Nanomaterials-Basel. 2021 Dec;11(12):3196
    24. [IF=2.633] Yong Tai et al."Silencing of circ_OSBPL10 affects the functional behaviors of oral squamous cell carcinoma cells by the miR-299-3p/CDK6 axis."Arch Oral Biol. 2022 Jan;:105363
    25. [IF=3.196] Peng Cao et al."Complecting the BiOCl nano-roundels based hollow microbasket induced by chitosan for dramatically enhancing photocatalytic activity."J Mol Struct. 2022 Apr;1254:132339
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    28. [IF=6.843] Zibo Zhang et al."Injectable double network hydrogel with hemostasis and antibacterial activity for promoting multidrug−resistant bacteria infected wound healing."Biomaterials Science. 2022 May;:
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